Champions League 5 clubs qualify for Round of 16 with two games to spare. After the Champions League group matches on Wednesday, at least five clubs have advanced to the Round of 16.
Only Real Madrid and Manchester City have advanced to the next round of elimination before Wednesday.
Bayern Munich, Club Brugge, and Napoli have joined them.
Bayern defeated Viktoria Plzen 4-2 to clinch their place.
Atletico Madrid and Club Bruges drew 0-0 to go to the knockout round of the Champions League for the first time.
The 18-time Belgian champions advance with an undefeated record despite not making it past the group stage in their previous 10 attempts.
Napoli advanced to the second round by defeating Ajax 4-2 in Naples.